“I knew from the second I met him that he was the love of my life,” the actress told Harper’s Bazaar UK of her husband who she wed in 2012 after four years of dating.

And though the pair can be rather low-key, hosting “house parties and dinner parties,” when they do hit the red carpet they certainly know how to turn on the star power.

Looking back at their more than decade-long marriage, here are some of the couple’s most adorable — and glamorous — moments caught on camera.

01of 09Stars Align

AXELLE/BAUER-GRIFFIN/FILMMAGIC

When it was time for Hathaway to receive a star on the Hollywood Walk of Fame, her hubby was right by her side to celebrate the milestone moment.

02of 09All Wrapped Up

Adam Shulman and Anne Hathaway.

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The two shared this sweet moment on the red carpet for the Valentino Haute Couture Spring Summer 2023 show during Paris Fashion Week in early 2023.

03of 09Stunning Stares

Anne Hathaway and Adam Shulman.

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Shulman couldn’t take his eyes off Hathaway at the Cannes Film Festival in 2023 where she absolutely stunned in this white sequined two piece gown.

04of 09Only Have Eyes For You

Adam Shulman and Anne Hathaway.

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When the pair stepped out to support the opening night of The Music Man on Broadway, Hathaway took a moment to look at her handsome partner as they walked the red carpet.

05of 09Cozied Up

Anne Hathaway and Adam Shulman.

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The actress nuzzled up next to her husband at the 2017 premiere of Colossal.

06of 09Woman of the Hour

Adam Shulman and Anne Hathaway.

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Shulman gave Hathaway her moment to shine at the 2016 Vanity Fair Oscar Party while she was pregnant with the couple’s first son, Jonathan Rosebank.

07of 09Hand in HandAdam Shulman and Anne Hathaway.

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For fashion’s biggest night in 2015, Hathaway opted for a gold cloaked number while Shulman went for a black and white tux (though if you look closely, you can see his golden pocket square to complement his wife’s look.)

08of 09Milestone Moment

Adam Shulman and Anne Hathaway.

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Shulman and Hathaway took a moment to bask in the glow of the actress’ first Oscar win for her performance in Les Misérables  at the 2013 Vanity Fair Oscar Party.

09of 09Sealed with a Kiss

Anne Hathaway and Adam Shulman.

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She also took home an award for the same performance earlier in the year at the 19th Annual Screen Actors Guild Awards. While celebrating the big night, the two shared a sweet kiss from their seats at the ceremony.